Hydrogeochemistry of coal mine water of North Karanpura coalfields,India: implication for solute acquisition processes,dissolved fluxes and water quality assessment

Mine water samples collected from different mines of the North Karanpura coalfields were analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness (TH), major anions, cations and trace metals to evaluate mine water geochemistry and assess solute acquisition processes, dissolved fluxes and its suitability for domestic, industrial and irrigation uses. Mine water samples are mildly acidic to alkaline in nature. The TDS ranged from 185 to 1343 mg L^?1 with an average of 601 mg L^?1. Ca²⁺ and Mg²⁺ are the dominant cations, while SO₄ ^2? and HCO₃ ^? are the dominant anions. A high concentration of SO₄ ^2? and a low HCO₃ ^?/(HCO₃ ^? + SO₄ ^2?) ratio (<0.50) in the majority of the water samples suggest that either sulphide oxidation or reactions involving both carbonic acid weathering and sulphide oxidation control solute acquisition processes. The mine water is undersaturated with respect to gypsum, halite, anhydrite, fluorite, aluminium hydroxide, alunite, amorphous silica and oversaturated with respect to goethite, ferrihydrite, quartz. About 40% of the mine water samples are oversaturated with respect to calcite, dolomite and jarosite. The water quality assessment shows that the coal mine water is not suitable for direct use for drinking and domestic purposes and needs treatment before such utilization. TDS, TH, F^?, SO₄ ^2?, Fe, Mn, Ni and Al are identified as the major objectionable parameters in these waters for drinking. The coal mine water is of good to suitable category for irrigation use. The mines of North Karanpura coalfield annually discharge 22.35 × 10⁶ m³ of water and 18.50 × 10³ tonnes of solute loads into nearby waterways.     

Identification of Water Conservation Sites in a Watershed (WRJ-2) of Nagpur District, Maharashtra using Geographical Information System (GIS) Technique

The paper deals with the application of Remote Sensing and Geographical Information System (GIS) technique for a watershed development program. For this study, the WRJ-2 watershed falling under Narkhed and Katol Tahsils of Nagpur district, Maharashtra, India is investigated. Various thematic maps (i.e. drainage, geology, soil, geomorphology and land use/ land cover) have been prepared using the remote sensing and GIS techniques. Initially, differential weightage values are assigned to all the thematic maps as per their runoff characteristics. Subsequently, the maps are integrated in GIS environment to identify potential sites for water conservation measures like gully plugs, earthen check dams, continuous contour trenches, percolation tanks, cement bandhara, afforestration and farm ponds, etc. The study depicts that the GIS technique facilitates integration of thematic maps and thereby helps in an identification of micro-zones each with unique characters in-terms of hydrogeology, thus amenable to specific water conservation techniques. It is therefore concluded that, the GIS technique is suitable for an identification of water conservation structures.     

Hydrogeochemical processes and quality assessment of groundwater in Dumka and Jamtara districts, Jharkhand, India

The hydrogeochemical study of groundwater in Dumka and Jamtara districts has been carried out to assess the major ion chemistry, hydrogeochemical processes and groundwater quality for domestic and irrigation uses. Thirty groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, anions (F^?, Cl^?, NO₃ ^?, HCO₃ ^?, SO₄ ^2?) and cations (Ca²⁺, Mg²⁺, Na⁺, K⁺). The analytical results show the faintly alkaline nature of water and dominance of Mg²⁺ and Ca²⁺ in cationic and HCO₃ ^? and Cl^? in anionic abundance. The concentrations of alkaline earth metals (Ca²⁺?+?Mg²⁺) exceed the alkali metals (Na⁺?+?K⁺) and HCO₃ ^? dominates over SO₄ ^2??+?Cl^? concentrations in the majority of the groundwater samples. Ca?CMg?CHCO₃ is the dominant hydrogeochemical facies in 60?% of the groundwater samples, while 33?% samples occur as a mixed chemical character of Ca?CMg?CCl hydrogeochemical facies. The water chemistry is largely controlled by rock weathering and ion exchange processes with secondary contribution from anthropogenic sources. The inter-elemental correlations and factor and cluster analysis of hydro-geochemical database suggest combined influence of carbonate and silicate weathering on solute acquisition processes. For quality assessment, analyzed parameter values were compared with Indian and WHO water quality standards. In majority of the samples, the analyzed parameters are well within the desirable limits and water is potable for drinking purposes. Total hardness and concentrations of TDS, Cl^?, NO₃ ^? _, Ca²⁺ and Mg²⁺ exceed the desirable limits at a few sites, however, except NO₃ ^? all these values were below the highest permissible limits. The calculated parameters such as sodium adsorption ratio, percent sodium (%Na) and residual sodium carbonate revealed excellent to good quality of groundwater for agricultural purposes, except at few sites where salinity and magnesium hazard (MH) values exceeds the prescribed limits and demands special management.     

Solar Activity,Lightning and Climate

The physics of solar forcing of the climate and long term climate change is summarized, and the role of energetic charged particles (including cosmic rays) on cloud formation and their effect on climate is examined. It is considered that the cosmic ray-cloud cover hypothesis is not supported by presently available data and further investigations (during Forbush decreases and at other times) should be analyzed to further examine the hypothesis. Another player in climate is lightning through the production of NO_x; this greenhouse gas, water vapour in the troposphere (and stratosphere) and carbon dioxide influence the global temperature through different processes. The enhancement of aerosol concentrations and their distribution in the troposphere also affect the climate and may result in enhanced lightning activity. Finally, the roles of atmospheric conductivity on the electrical activity of thunderstorms and lightning discharges in relation to climate are discussed.     

Lightning activity and its relationship with typhoon intensity and vertical wind shear for Super Typhoon Haiyan (1330)

Super Typhoon Haiyan (1330), which occurred in 2013, is the most powerful typhoon during landfall in the meteorological record. In this study, the temporal and spatial distributions of lightning activity of Haiyan were analyzed by using the lightning data from the World Wide Lightning Location Network, typhoon intensity and position data from the China Meteorological Administration, and horizontal wind data from the ECMWF. Three distinct regions were identified in the spatial distribution of daily average lightning density, with the maxima in the inner core and the minima in the inner rainband. The lightning density in the intensifying stage of Haiyan was greater than that in its weakening stage. During the time when the typhoon intensity measured with maximum sustained wind speed was between 32.7 and 41.4 ms^?1, the storm had the largest lightning density in the inner core, compared with other intensity stages. In contrast to earlier typhoon studies, the eyewall lightning burst out three times. The first two eyewall lightning outbreaks occurred during the period of rapid intensification and before the maximum intensity of the storm, suggesting that the eyewall lightning activity could be used to identify the change in tropical cyclone intensity. The flashes frequently occurred in the inner core, and in the outer rainbands with the black body temperature below 220 K. Combined with the ECMWF wind data, the influences of vertical wind shear (VWS) on the azimuthal distribution of flashes were also analyzed, showing that strong VWS produced downshear left asymmetry of lightning activity in the inner core and downshear right asymmetry in the rainbands.     

Chemical characterization of wet precipitation events and deposition of pollutants in coal mining region,India

The present study investigated the chemical composition of wet atmospheric precipitation in India’s richest coal mining belt. Total 418 samples were collected on event basis at six sites from July to October in 2003 and May to October in 2004 and analysed for pH, EC, F⁻, Cl⁻, , , Ca²⁺, Mg²⁺, Na⁺, K⁺ and . The average pH value (5.7) of the rainwater of the investigated area is alkaline in nature. However, the temporal pH variation showed the alkaline nature during the early phase of monsoonal rainfall but it trends towards acidic during the late and high rainfall periods. The rainwater chemistry of the region showed high contribution of Ca²⁺ (47%) and (21%) in cations and (55%) and Cl⁻ (23%) in anionic abundance. The high non seas salt fraction (nss) of Ca²⁺ (99%) and Mg²⁺ (96%) suggests crustal source of the ions, while the high nss (96%) and high ratio signifying the impact of anthropogenic sources and the source of the acidity. The ratio of varies from 0.03 to 3.23 with the average value of 0.84 suggesting that Ca²⁺ and play a major role in neutralization processes. The assessment of the wet ionic deposition rates shows no any specific trend, however Ca²⁺ deposition rate was highest followed by and _.